Ten vinegar samples were collected from the Libyan local market in the city of Tripoli. The elements have been investigated were:As, Pb, Cu, Fe and Zn. The samples were treated and prepared according to Indian standard IS 14703-1999, and the measurements have been done by using inductively coupled plasm – atomic emission spectroscopy (ICP-AES) available in the Libyan Petroleum Institute. The analysis indicated that the concentration of Arsenic of all the samples was less than 0.02mg/kg whereas, the concentration of lead is less than 0.03mg/kg. The concentration ranges of Cu, Fe and Zn were 0.11-0.59mg/kg, 0.72-2.67mg/kg and 0.08-0.28mg/kg respectively. The concentrations of the elements AS, Pb, Cu, Fe and Zn are within the limits of a variety of standards such as Libyan, Indian and Pakistani ones. arabic 21 English 134
ABUBAKER A BASHIR ATRROG, RAGIAB ALI MOKHTAR ISSA, ِAburawi Mohammed Aburawi Algornazi(11-2020)

Ternary systems of 152Eu(III), bulk bentonite and ethylenediaminetetraacetic acid (EDTA) ([Eu] = 7.9 × 10−10 M; pH = 6.0–7.0) have been studied. Without EDTA, there was slow uptake in a two-stage process, with initial rapid sorption of Eu(III) (96%), followed by slower uptake of a much smaller fraction (3.0% over a period of one month). The reversibility of Eu(III) binding was tested by allowing Eu(III) to sorb to bentonite for 1–322 days. EDTA was added to the pre-equilibrated Eu bentonite systems at 0.01 M, a concentration that was sufficient to suppress sorption in a system where EDTA was present prior to the contact of Eu(III) with bentonite. A fraction of the Eu was released instantaneously (30‒50%), but a significant amount remained bound. With time, the amount of Eu(III) retained by the bentonite reduced, with a slow fraction dissociation rate constant of approximately 4.3 × 10−8 s−1 (values in the range 2.2 × 10−8 – 1.0 × 10−7 s−1) for pre-equilibration times ≥7 days. Eventually, the amount of Eu(III) remaining bound to the bentonite was within error of that when EDTA was present prior to contact (4.5% ± 0.6), although in systems with pre-equilibration times >100 days, full release took up to 500 days. Europium interactions with colloidal bentonitewere also studied, and the dissociation rate constant measured by a resin competition method. For the colloids, more Eu was found in the slowly dissociating fraction (60–70%), but the first-order dissociation rate constant was faster, with an average rate constant of 8.8 × 10−7 s−1 and a range of 7.7 × 10−7–9.5 × 10−7 s−1. For both bulk and colloidal bentonite, although slow dissociation was observed for Eu(III), there was no convincing evidence for ‘irreversible’ binding.
RAGIAB ISSA(1-2021)

تحضير ودراسة فاعلية بعض المركبات الاميدية الجديدة
Asma Omar jebril (1-2012)