Abstract Matrix acidizing is a stimulation method commonly used to remove near wellbore damage and restore original formation permeability. It involves the injection of acid into formations at pressures below the fracture pressure. Acid flows down the well into the reservoir, and then reacts with the rock such that any near wellbore permeability damage created by meling or completion fluids can be removed and apparent permeability increased. A matrix acidizing treatment can be' applied to either a sandstone or a carbonate reservoir. Different acids are used because different minerals are involved in these treatments. Hydrochloric acid (HCI) is usually used in carbonate reservoirs to react with carbonates. Hydrofluoric acid (HF) or mixture of Hydrofluoric acid (HF) with Hydrochloric acid (HCI) is commonly used in sandstone porous media to react with silicates and feldspars in the rock. Since the mechanisms of acid reactions with these two types of rock are different, results of the treatments are different as well. In sandstone matrix acidizing, permeability increase behind the acid front is relatively homogeneous. The flow and reaction of acid in carbonate porous media results in the formation of highly conductive flow channels, commonly referred to as wormholes. In the present work we have studies the first study to test the optimal acid flux theory presented by Wang (1) with several independent sets of experimental data. The model was comparing with field data. The second study we use model presented by McCune and Fogler.(2) This previous studies on mathematical modeling of the chemical reactions between sandstone and mud acid. This model is lumped-parameter model. The lumped-parameter model simplifies the chemistry of the dissolution of sandstone minerals with mud acid. The models are compared with the experimental data at different flow rates.
عبد ربه ادريس بوسدرة (2010)

Abstract Recently more than 150 million tonnes of plastics were produced in the world. On the one hand, the consumption and production of polymers are increasing, on the other hand as landfill and incineration become more expensive and less accepted .The increasing amount of polymer wastes from them generates further mainly environmental problems. The recycling of plastic wastes is gaining increasing importance. Pyrolysis is one promising method for the treatment of mixed and contaminated plastic wastes. In this way the plastic wastes are converted into fuels or other valuable feedstock for the petrochemical industry. In present work catalytic cracking of waste plastics blend with HGO [Libyan gas oil supplied by the Zawia Oil Refinery Company boils in the range of 275-375Cº] was investigated using H-ZSM5and H-BETA. Reaction systems that were studied included high density polyethylene HDPE and polypropylene blend with HGO, reactions were carried out in one litre micro autoclave reactor under different conditions of weight, temperature and type of catalyst, The optimum conditions were 2.5% catalyst by weight of total feed stock, one hour, atmospheric presser and three temperatures selected 400Cº, 425Cº and 450Cº. The product distribution for the system [plastics and HGO] provided some good results high yield of liquid [gasoline] up to 210Cº, gases and small amount of heavy oils. Some analysis was used to qualify and quantify the product. The results from GC.MS analysis showed that the yield of gasoline (c5-c12) over H-ZSM5 higher than H-BETA. In case of 5%PP, 15%HDPE and 80%HGO over H-ZSM5 at 450Cº, 96% total conversion achieved. The result from TGA in the same case is 15% by weight. Also the theoretical calculations to quantify the produced gases after burring of waste plastic in rotary kiln reactor have been evaluated. it is found that the suitable ratio of CO:H2 to produce methanol is 7:1
بسمة محمود التونسي (2010)

Abstract This study is to develop the specifications of the present cement products so as to comply with the quality and quantities requirements of the local market. The subject of this thesis is to present the results of a series of laboratory trials on a number of raw material mixtures prepared to produce moderate and high sulfate resistance cement at EL- Mergheb cement factory which currently produces ordinary Portland cement. At first, six different raw material sample mixtures were prepared from marlstone,marl and iron ore. The clinker (cement ) produced from these samples was within the moderate sulfate resistance cement ( MSRC ) specifications which mainly requires the tri calcium aluminate (C3A) to be less than 8 % by weight. The trial runs on other three raw material samples made that from mixing marlstone , clay , and iron ore produced clinker specifications that were out of those for MSRC namely, C3A is greater than 8 % . This means that the addition of clay to the raw mix prevents the production of cement with MSRC specifications. This was due to the high percentage of Al2O3 in the clay . The specifications of the clinker products based on these results , MSRC was successfully produced at the factory from raw material mixtures ( marlstone, marl and iron ore ) without any clay addition . Finally three raw mix samples were prepared from marlstone, marl, iron ore, and sand and tested in the laboratory to explore the possibility of producing high sulfate resistance cement ( HSRC) which requires C3A to be less than 5 % . The results of these laboratory trials showed that when the sand in the raw mix is kept under 1.80 % , the produced clinker specifications are within those of HSRC. The permission to carry out these trials in the factory is underway. The expected economic benefits from producing both MSRC and HSRC is highly feasible. Both types will be sold in local market without any additional operating or capital costs .
صالح محمد صالح (2013)